No. 25 (2018): GFS
RICERCJIS

The EOX parameter in characterisation of sewage sludge in Friuli Venezia Giulia

DANIELE GOI
Dipartimento Politecnico di Ingegneria e Architettura, University of Udine, Udine, Italy
ALI KHAKBAZ
Dipartimento Politecnico di Ingegneria e Architettura, University of Udine, Udine, Italy

Peraulis clâf

  • EOX, Sewage sludge, Agricultural use

Cemût citâ

[1]
GOI, D. and KHAKBAZ, A. 2018. The EOX parameter in characterisation of sewage sludge in Friuli Venezia Giulia. Gjornâl Furlan des Siencis - Friulian Journal of Science. 25, 25 (May 2018), 77–82.

Ristret

Sewage sludge generated from wastewater treatment plants (WWTPs) has attracted greater attention because of its potential for improving soil properties and for providing important nutrient and trace element supplements that are essential for plant growth. In agricultural use of sewage sludge the pollutant risk for all sludge should be specifically evaluated due to the different characteristics of different types of sludge, which undergo different levels of treatment, as well as the extensive and variable nature of wastewater pollutant inputs. Sewage sludge generated from wastewater treatment plants in Friuli Venezia Giulia region were analysed to evaluate the extractable organic halogen (EOX) concentration. Ethyl acetate and n-hexane were used as extraction solvents and EOX values were determined coulometrically and compared with respect to the potential of solvents and size of WWTPs. For all sewage sludge samples, the obtained results proved ethyl acetate to be a more effective solvent in EOXdetermination. It was found that sewage sludge from small WWTPs are more suitable for agricultural use due to their low concentration of EOX.

Riferiments

  1. Asplund G., Grimvall A. (1991). Organohalogens in nature. Environmental Science & Technology, 25: 1346-1350.
  2. Contreras Lopez M.C. (2003). Determination of potentially bioaccumulating complex mixtures of organochlorine compounds in wastewater: a review of Environment International, 28: 751-759.
  3. Goi D., Tubaro F., Dolcetti G. (2006). Analysis of metals and EOX in sludge from municipal waste water treatment plants: a case study. Waste management, 26: 167-175.
  4. Hayer F., Wagner P., Pihan J.C. (1996). Monitoring of extractable organic halogens (EOX) in chlorine bleached pulp and paper mill effluents using four species of transplanted aquatic mollusks. Chemosphere, 33: 2321-2334.
  5. Kannan K., Falandysz J., Yamashita N., Tanabe S., Tatsukawa R. (1992). Temporal trends of organochlorine concentrations in cod liver oil from the Southern Baltic Proper 1971-1989. Marine Pollution Bulletin, 24: 358-363.
  6. Kannan K., Kawano M., Kashima Y., Matsui M., Giesy J.P. (1999). Extractable organohalogens (EOX) in sediment biota collected at an Estuarine March near a former chloroalkali facility. Environmental Science & Technology, 33: 1004-1008.
  7. Langenkamp H., Part P., Erhardt W., Prüeß A. (2001). Organic contaminants in sewage sludge for agricultural use. Report JRCISPRA. Institute for Environment and Sustainability – Soil and Waste Unit. 18/10/2001.
  8. Reemtsma T., Jekel M. (1996). Potential of ethyl acetate in the determination of Extractable Organic Halogens (EOX) from contaminated soil, sediment, and sewage sludge. Chemosphere, 32(5): 815-826