Study of the Formation-Distribution of Chlorite and Chlorate from Chlorine Dioxide in a Water Distribution Network: the Case Study of Udine
Keywords
- Disinfection by-products,
- Chlorine dioxide,
- EPANET-MSX
How to Cite
Abstract
To ensure water quality and to avoid bacterial contamination in Drinking Water Distribution Systems (DWDS), disinfection is conducted in drinking awater treatment plants. Disinfectant concentration in DWDS decreases with time while, due to chemical reactions with dissolved and particulate matter, biofilm and pipe wall material, disinfection by-product (DBP) formation increases. Chlorine-based disinfection methods are the most commonly used and, if chlorine dioxide is used as a disinfectant, chlorite and chlorate can be produced as DBPs. This study evaluates with a simulation model (EPANET MSX) the formation and distribution of chlorite and chlorate in the water distribution system of Udine, which is disinfected with chlorine dioxide. Having an integrated chemical-hydraulic model can, in fact, improve water utilities network management both in standard and special conditions. The results obtained with the simulation model were only minimally different to the concentration values measured on site, hence it can be assumed that they may be used for several conditions in order to make predictions.
References
- Al-Jasser A.O. (2007). Chlorine decay in drinking-water transmission and distribution systems: pipe service age effect. Water Research 41, 2: 387-396.
- Boano F., Fiore S., Revelli R. (2016). Chlorate formation in water distribution systems: a modeling study. Journal of Hydroinformatics, 18, 1: 115.
- Kiéné L., Lu W., Lévi Y. (1998). Relative importance of the phenomena responsible for chlorine decay in drinking water distribution systems. Water Science and Technology, 38, 6: 219-227.
- Korn C., Andrews R.C., Escobar M.D. (2002). Development of chlorine dioxide-related by product models for drinking water treatment. Water Research, 36, 1: 330-342.
- Rossman L.A. (2000). EPANET 2.0 User’s Manual. Washington, DC: United States Environmental Protection Agency.
- Sorlini S., Biasibetti M., Gialdini F., Muraca A. (2016). Modeling and Analysis of Chlorine Dioxide, Chlorite, and Chlorate Propagation in a Drinking Water Distribution System. Journal of Water Supply: Research and Technology-Aqua, 65: 597-611.
- Wable O., Dumoutier N., Duguet J.P., Jarrige P.A., Gelas G., Depierre J.F. (1991). Modelling chlorine concentrations in a network and applications to Paris distribution network. Water quality modeling in distribution systems. Proceedings of the American Water Works Association Research Foundation Conference, Water Quality Modeling in Distribution Systems. Cincinnati, OH, pp. 265-276.
- WHO (2011). Guidelines for Drinking Water Quality, 4th edn. Geneva, Switzerland: World Health Organization.
- Zhang G.R., Kiéné L., Wable O., Chan U.S., Duguet J.P. (1992). Modelling of chlorine residual in thewater distribution network of Macao. Environmental Technology, 13, 10: 937-946
