No. 14 (2010): GFS
RICERCJIS

Development of a modified co-precipitation route for thermally resistant, high surface area ceria-zirconia based solid solutions

ALFONSINA PAPPACENA
Department of Chemistry, Physics and the Environment, University of Udine, Udine, Italy.

Peraulis clâf

  • Ceria-zirconia,
  • TWC,
  • OSC,
  • surface area,
  • surfactant

Cemût citâ

[1]
PAPPACENA, A. 2010. Development of a modified co-precipitation route for thermally resistant, high surface area ceria-zirconia based solid solutions. Gjornâl Furlan des Siencis - Friulian Journal of Science. 14, 14 (Jan. 2010), 119–124.

Ristret

In this work a modified co-precipitation route for ceria-zirconia based material with a high surface area, high thermal stability and enhanced OSC properties has been developed and the importance of the addition of surfactants and H2O2 in order to promote the stability of these materials at high temperatures has been developed.

Riferiments

  1. Djuricˇic´ B., Pickering S. (1999). Nanostructured cerium oxide: preparation and properties of weakly-agglomerated powders. Journal of the European Ceramic Society, 19 (11): 1925-1934.
  2. Kaspar J., Fornasiero P. (2003). Nanostructured materials for advanced automotive de-pollution catalysts. Journal of Solid State Chemistry, 171 (1-2): 19-29.
  3. Larcher O., Monin D., Rohart E., Rhodia Elect & Catalysis, Pat. Appl. FR 2852596(A1), 2009.
  4. Mamontov E., Brezny R., Koranne M., Egami T. (2003). Nanoscale Heterogeneities and Oxygen Storage Capacity of Ce0.5Zr0.5O2. Journal of Physical Chemistry B, 107 (47): 13007-13014.
  5. Ozawa M., Hattori M. (2006). Ultrasonic vibration potential and point of zero charge of some rare earth oxides in water. Journal of Alloys and Compounds, 412: 560-562.
  6. Terribile D., Trovarelli A., Llorca J., de Leitenburg C., Dolcetti G. (1998). The preparation of high surface area CeO2–ZrO2 mixed oxides by a surfactant-assisted approach. Catalysis Today, 43 (1-2): 79-88.
  7. Trovarelli A. (Ed.) (2002). Catalysis by Ceria and Related Materials. London: Imperial College Press.
  8. Wakita T., Kohara A, Kann Y., Omoto H., Daiichi Kigenso and Chemcat Corp, Eur. Pat. Appl. EP 1801074 (A1), 2007.
  9. Yu P., Hayes S. A., O’Keefe T. et al. (2006). The Phase Stability of Cerium Species in Aqueous Systems. Journal of the Electrochemical Society, 153 (1): C74-C79.
  10. Zhang Q., Wang W., Goebl J., Yin Y. (2009). Self-templated synthesis of hollow nanostructures. Nano Today, 4 (6): 494-507.